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Preheat an oven to 300°F. Generously coat the cups of a 12-cup miniature muffin pan with butter.
Thinly slice the asparagus spears crosswise, keeping the tips whole. Set the tips aside.
In a sauté pan over medium-low heat, melt 2 tsp. of the butter. Add the sliced asparagus and the leek and cook gently, stirring often, until just slightly softened, 1 to 2 minutes. Transfer to a small bowl and let cool.
Crumble the goat cheese into a bowl. Add the ricotta cheese and egg and mash together with a fork until well combined, and then mix in the cooled vegetables. Divide the filling evenly among the prepared muffin cups. Bake the bites until puffed and lightly golden on top, 20 to 25 minutes.
Meanwhile, cut each asparagus tip in half lengthwise. In a small nonstick fry pan over low heat, melt the remaining 1/2 tsp. butter. Add the asparagus tips and sauté until just tender, about 1 minute. Transfer to a small bowl.
When the bites are done, transfer the pan to a wire rack. Run a table knife around the inside of each cup to loosen the edges and then let cool slightly. Invert a large plate or tray over the muffin pan, invert the pan and plate together, and lift off the pan.
Arrange the bites on a platter or individual plates and top each with an asparagus-tip half. Serve warm or at room temperature.
Makes 12 bites; serves 6 to 12.
Adapted from Williams-Sonoma New Flavors for Appetizers, by Amy Sherman (Oxmoor House, 2008).